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Above Bandgap Voltages from Ferroelectric Photovoltaic Devices Form

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we have arrived to the question how do molecular bonds determine the band gap we have discussed that the silicon atom has four outer electrons these four outer electrons play an important role in making the bones with other atoms in a molecule or in a solid these electrons are the so-called valence electrons in a very cruel simplification a bond can be considered as the mixing of two orbitals of neighboring atoms one valence electron shares its orbital with the orbital of a valence electron of a neighboring atom this means that it takes two valence electrons to make one valence bond this resulting orbital is called a molecular orbital from nature we know that the orientation of a silicon bond is tetrahedral-like consider the lattice of crystalline silicon which is a diamond cubic crystalline lattice looking at a single atom in such letters the angle between all four bonds is 109 degrees however if we look at the orbitals of the four valence electrons in the third shell of silicon we do

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