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 CFT D5 FI 091713 Indd 2013-2025

Ohio D5 2013-2025 Form

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Professor Dave here, I wanna tell you about crystal field theory. As we just learned, coordination compounds have some very interesting geometries, and many of these can’t be explained using the same models that we use for normal covalent compounds, like VSEPR theory or valence bond theory, since the type of bonding involved is more complex than mere overlapping of hybridized orbitals. Instead, we have to use another model called crystal field theory, so let’s go through the finer points of this theory now. Crystal field theory is based on the premise that the metal ion and the ligands can be treated as point charges, and the spatial arrangement of these point charges will affect the energies of the d orbitals for the central metal atom. These are the orbitals that ligands donate electron density into, so these are the chief concern for the model, and this model, although incomplete just like VSEPR theory or valence bond theory, does wonderfully explain things like the colors, magn

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