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so as you remember the first semester we studied bonding and molecular structure and then toward the end we did some sort of thermodynamics which is what connects structure to energy which is what determines what chemistry will happen so this semester we're going to talk about that chemistry about reaction mechanisms and about using these reactions to do synthesis and we'll also do some spectroscopy around the middle of the semester so just a brief excursion through what we're going to be doing the first two quarters of the semester are going to be on how mechanisms are discovered and understood in terms of structure and energy what we talked about last time so first we'll look naturally enough at the simplest reactions there can't be anything much simpler than just cleaving a bond but remember there's also the possibility of making a bond at the same time you break a bond and we introduced these ideas last semester of course so we're going to start with free-radical substitution one o

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