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Get and Sign Chem 2600 MT2A BS2014b University of Lethbridge 2014-2022 Form

Get and Sign Chem 2600 MT2A BS2014b University of Lethbridge 2014-2022 Form

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Order in which you incorporate your substituents. OCH3 i H3C There are two possible factors that may account for the difference in reactivity electronic and/or steric. Explain. The methyl group is an electron donor and/or will raise the LUMO so would electronically deactivate the dienophile. Explain. Both trans double bonds in the diene - this bonds are cis in the adduct. The dienophile is trans - these bonds are trans in the product. Iii 2-t-Butylbutadiene reacts 27 times faster than butadiene...

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So as you remember the first semester we studied bonding and molecular structure and then toward the end we did some sort of thermodynamics which is what connects structure to energy which is what determines what chemistry will happen so this semester we're going to talk about that chemistry about reaction mechanisms and about using these reactions to do synthesis and we'll also do some spectroscopy around the middle of the semester so just a brief excursion through what we're going to be doing the first two quarters of the semester are going to be on how mechanisms are discovered and understood in terms of structure and energy what we talked about last time so first we'll look naturally enough at the simplest reactions there can't be anything much simpler than just cleaving a bond but remember there's also the possibility of making a bond at the same time you break a bond and we introduced these ideas last semester of course so we're going to start with free-radical substitution one o

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