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changing the ph of a solution can affect the solubility of a slightly soluble salt for example if we took some solid lead to fluoride which is a white solid and we put it in some distilled water the solid is going to reach an equilibrium with the ions in solution lead to fluoride forms lead to plus ions and fluoride anions and a one to two mole ratio so if we have two lead two plus ions in this diagram we need four fluoride anions at equilibrium the rate of dissolution is equal to the rate of precipitation and therefore the amount of solid and the concentration of ions in solution remains constant and this forms a saturated solution of lead ii fluoride to the system at equilibrium we're going to add some h plus ions so by increasing the concentration of h plus ions in solution we're decreasing the ph of the solution when the h plus ions are added to the solution most of them react with the fluoride anions that are present so h plus plus f minus forms hf comparing the fi

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